X-ray induced disulfide bond cleavage studied with EPR, optical absorption and X-ray diffraction
نویسندگان
چکیده
منابع مشابه
Insights into the mechanism of X-ray-induced disulfide-bond cleavage in lysozyme crystals based on EPR, optical absorption and X-ray diffraction studies
Electron paramagnetic resonance (EPR) and online UV-visible absorption microspectrophotometry with X-ray crystallography have been used in a complementary manner to follow X-ray-induced disulfide-bond cleavage. Online UV-visible spectroscopy showed that upon X-irradiation, disulfide radicalization appeared to saturate at an absorbed dose of approximately 0.5-0.8 MGy, in contrast to the saturati...
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The short-range order of K P 0 3 glass has been studied by diffraction methods in order to make evident the different behaviour of the P-O bonds within the P 0 4 tetrahedron. The oxygen sites are devided into bridging and terminal (non-bridging) oxygen sites, corresponding to two P 0 bond lengths, the difference of which amounts to 14.5 pm. Previous conclusions about the changes of the P 0 bond...
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where the peak shapes were described by a pseudo-Voigt function and the background was modeled with an 6-term polynomial. Additionally, the PXRD patterns obtained at room temperature and 100 K were analyzed by Le Bail refinement using the GSAS and EXPGUI software, 2,3 where the peak shapes were described by a pseudo-Voigt function (CW profile function 3) and the background was modeled with an 4...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2013
ISSN: 0108-7673
DOI: 10.1107/s0108767313099248